The thick liquid used to be called "oil of vitriol," since it was originally made by the distillation of "green vitriol," or iron sulfate as we know it today. It was so corrosive and nasty that the term "vitriolic" entered our vocabulary to describe language that was particularly disagreeable.
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Sulfuric acid is the substance that, in movies at least, sizzles through metal, burns skin and dissolves corpses. Although in real life it is not quite as deadly as in works of fiction, it is bad enough. We sometimes use it as a drain cleaner to dissolve all the accumulated guck which includes items ranging from hair to toothpaste tube caps. There is an important point worth noting about using concentrated sulfuric acid as a drain cleaner. It must never be mixed with any of the other commonly available drain cleaners which are based on lye (sodium hydroxide). Combining these two generates a tremendous amount of heat, enough to melt plastic pipes, as well as toxic acid vapors!
So if sulfuric acid is so dangerous, why are their tankers and trains criss-crossing the continent loaded with this liquid? The reason is actually simple. Sulfuric acid is the world's most important industrial chemical! In North America we produce about 50 million tons a year, mostly by burning sulfur to form sulfur dioxide which is then reacted with water. Why do we need all that sulfuric acid? Primarily to produce fertilizer. Sulfuric acid converts insoluble phosphate ore into a valuable fertilizer known as "superphosphate." Without this we could not even contemplate feeding the world. Then there are the detergents, the dyes, the drugs, the explosives, the paints, the metals and the car batteries, all of which require sulfuric acid for production.
Sulfuric acid also occurs in nature. Oil, coal and gasoline all contain small amounts of naturally occurring sulfur compounds. When these burn, their sulfur content is released as sulfur dioxide, a gas that eventually combines with moisture to form sulfuric acid. Presto, we have acid rain! In some areas the rain can be acidic enough to corrode limestone used in building construction. Limestone is calcium carbonate and reacts with sulfuric acid to form carbon dioxide and calcium sulfate that is washed away.
Many years ago during a lecture on acid rain I decided to demonstrate its effects by opening a bottle of the acid and hanging a nylon stocking nearby. The acid vapours soon formed large holes in the stocking. The students were impressed and undoubtedly learned something about acid rain. But I learned something too. I learned about the popularity of nylon underwear! The next day I was confronted by a couple of students who had gone home at night and discovered holes in their finery. Apparently the sulfuric acid vapours had a more wide ranging effect than I had expected. There was some explaining to do in the face of some pretty vitriolic language.
@JoeSchwarcz
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The chemical manufacturing industry is a key global industry that encompasses many thousands of companies producing a wide range of products, from laboratory analytical reagents, solvents, and custom-made chemicals to pharmaceuticals.
This industry supplies virtually all manufacturing companies, which use different types of chemicals for different purposes, including cleaning agents, solvents, reactants, and ingredients.
What Is the Global Usage of Chemicals?The global chemical usage can be categorised in terms of amount (volume and weight) and in terms of unit usage.
For example, sulphuric acid (H2SO4) is virtually ubiquitous because of its many applications in manufacturing other products. In fact, it's estimated that the global annual global demand for sulphuric acid will be around 400 metric tonnes by the year . Currently, it is about half that projected global demand.
The chemicals used by industries and end-users can be classified into categories or segments.
According to Statista, in some segments of the chemical industry posted growth, while other segments experienced decline. For example, chemical coatings showed a 2.7% growth, while organics posted a negative growth of -2.2%. Of course, this implies corresponding increase or decrease in the global demands for these products.
Looking forward, it's expected that the global production and corresponding demand for chemical products remains on a similar trend, with a few adjustments and slight differences on the microeconomic level.
Key TakeawaysCommon chemicals can be categorised into various segments or types
Specific chemicals can be ranked into 10 commonly used in the chemical industry
The most common chemicals have various applications, but are commonly used as reactants or precursors to manufacture other chemicals
The top ten chemicals in the world are the basic elements and compounds that are used across various industries in bulk, particularly in chemical manufacturing.
These chemicals are typically simple, react easily with other chemicals, and used to manufacture other chemicals.
Depending on the type of chemical being manufactured, the fundamental chemicals are applied in various ways, such as reagents, solvents, catalysts, precursors, reactants, and ingredients.
Here are the top ten examples of industrial chemicals used worldwide:
Sulfuric Acid (H
2
SO
4
)
Nitrogen (N
2
)
Ethylene (C
2
H
4
)
Oxygen (O
2
)
Propylene (C
3
H
6
)
Chlorine (Cl
2
)
Ethylene Dichloride (C
2
H
2
Cl
2
)
Phosphoric Acid (H
3
PO
4
)
Ammonia (NH
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3
)
Sodium Hydroxide (NaOH)
Let's look at each of these in a little more detail'
1. Sulphuric Acid (H
2
SO
4
)
Sulfuric acid is the most common chemical used in industry, particularly in the manufacture of fertilisers. It is primarily used as a reactant to manufacture phosphoric acid, which is then used as a precursor.
2. Nitrogen (N
2
)
Nitrogen naturally exists in the atmosphere as diatomic elemental molecules. In fact, about 78% of the atmosphere is nitrogen.
It is industrially converted into ammonia through the Haber'Bosch process, and is also used as a blanketing gas to protect oxygen-sensitive products like fruits and vegetables.
Liquid nitrogen is widely used in laboratories to preserve specimens and conduct scientific experiments.
3. Ethylene (C
2
H
4
)
Ethylene is a hydrocarbon that's mainly used as fuel, and is produced in large volumes worldwide. Almost 95% of ethylene produced annually is through the process of steam cracking of petroleum hydrocarbons. Different types of feedstocks, such as ethane, propane, butane, and naphtha, are used in the production of ethylene.
4. Oxygen (O
2
)
Just like nitrogen, oxygen exists naturally in the atmosphere as diatomic molecules. About 21% of the atmosphere is composed of oxygen.
In industry, oxygen is one of the three ingredients of combustion (the other two being fuel and heat). Commercially, oxygen is used for oxy-acetylene and oxyhydrogen welding torches, in SCUBA diving, and in healthcare.
As a major oxidant, oxygen is also used in various industrial chemical processes, such as the breakdown of hydrocarbons into simpler hydrocarbons like ethylene and acetylene. These are then used in the production of plastics paints and plastics, as well as other products.
Finally, liquid oxygen, along with liquid hydrogen, is used as cynic propellant. Around 550,000 litres of liquid oxygen is used per space shuttle launch.
5. Propylene (C
3
H
6
)
There are several products that are manufactured out of propylene. These include polypropylene, which is a versatile plastic material used to make other products, such as material used in packaging, automotive parts, and textiles.
Propylene is also the main feedstock for synthesising other materials, such as acrylic acid. It is essential in manufacturing polyurethane.
6. Chlorine (Cl
2
)
Chlorine is one of the most reactive elements. This halogen gas exists as a diatomic molecule, but it is seldom found in nature as an element because of its high reactivity.
It is a powerful oxidising agent that is industrially produced through the electrolysis of sodium chloride brine. It's mainly used for water treatment to kill pathogens, as the active ingredient of bleaches and detergents, and to bleach paper and textiles.
7. Ethylene Dichloride (C
2
H
2
Cl
2
)
Ethylene dichloride is important in the production of PVC. It's also essential in the synthesis of polystyrene, a type of synthetic polymer. Many consumer goods and packaging materials are made out of polystyrene.
8. Phosphoric Acid (H
3
PO
4
)
Phosphoric acid is industrially produced from phosphate rocks and is essential in the synthesis of phosphate fertilisers. It's also an important chemical in the pharmaceutical industry as it's used in the manufacture of anti-nausea medicines, mouthwash products, and teeth whitening products. It's also used in the food industry as an additive to cheese, jams, cereals, and carbonated drinks.
9. Ammonia (NH
3
)
Ammonia is manufactured on an industrial scale using the Haber-Bosch process, which involves high heat and pressure and iron metal catalyst. It combines atmospheric nitrogen with hydrogen.
About 70% of industrially produced ammonia is used to manufacture fertilisers. Other applications of ammonia include refrigeration, water purification, manufacturing explosives, plastics, textiles, dyes, and other products.
10. Sodium Hydroxide (NaOH)
Sodium hydroxide is a strong alkaline compound mainly used as an ingredient in manufacturing soaps and detergents. It also has a wide range of applications in other industries, such as in the petroleum industry for creating the right pH when drilling in the earth. It's also used in the paper industry for separating the fibres of cellulose in wood.
Conclusion
Chemicals are an integral part of industry, and we are all consumers of various types of chemicals. Some chemicals are fundamentally important because they serve as the basis of manufacturing other chemicals, and some are virtually ubiquitous across industries worldwide.
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